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Chromium speciation by TXRF analysis

Kallithrakas-Kontos Nikolaos, Koulouridakis Pavlos, Χατζησταύρος Βασίλειος, Αρετάκη Ιωάννα

Πλήρης Εγγραφή


URI: http://purl.tuc.gr/dl/dias/A15D8045-CA82-465A-A7DF-2B761168C568
Έτος 2009
Τύπος Δημοσίευση σε Περιοδικό με Κριτές
Άδεια Χρήσης
Λεπτομέρειες
Βιβλιογραφική Αναφορά N. Kallithrakas-Kontos, P. Koulouridakis, V. Hatzistavros and I. N. Aretaki, "Chromium speciation by TXRF analysis," X-Ray Spectrom., vol. 38, no. 2, pp. 152–156, Jan. 2009. doi:10.1002/xrs.1141 https://doi.org/10.1002/xrs.1141
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Περίληψη

Chromium (Cr) is an element which usually occurs in two different forms, Cr(III) and Cr(VI). As Cr(VI) is much more toxic than Cr(III), no complicated analytical methods with low detection limit are needed for chromium speciation. In the present work, a new method is presented for chromium speciation at low concentrations by selective membrane collection and total Reflection x-ray fluorescence (TXRF) analysis. Various membranes were produced on the surface of quartz reflectors containing different complexing ligands in Nafion and poly vinyl chloride (PVC) matrices. The membranes were produced on the surface of quartz glass, while the reflectors were immersed in water solutions with low concentrations of chromium salts for many hours. When the equilibration stage was achieved, the reflectors were analyzed by TXRF. Completely selective membranes for Cr(III) and Cr(VI) were prepared with minimum detection limits lower than 0.6 ng.ml−1 (ppb) in drinking water

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